Fluorous

Membership in and service to professional societies can play a significant role in shaping the future of our field, and I am proud of the work done by the American Chemical Society to advance chemistry for the benefit of our world and all its people." Bazzi's research interests focus on metathesis chemistry as a powerful tool in small molecule and polymer synthesis, in addition to polymer-supported catalysis, DNA-mimetic polymers and fluorous analogs of ruthenium-based catalysts.

We are proud of what he has accomplished in his own career and on behalf of our university, and this prestigious recognition is just one more example of his excellence, integrity and leadership." Bazzi's research interests focus on metathesis chemistry as a powerful tool in small molecule and polymer synthesis, in addition to polymer-supported catalysis, DNA-mimetic polymers, and fluorous analogs of ruthenium-based catalysts.

Lentijo et al., "Fluorophobic effect in metallomesogens-the synthesis and mesomorphism of Ag, Au, Cu, Fe, Pd, and Pt fluorous isocyanide complexes," European Journal of Inorganic Chemistry, vol.

NaHSO4*H2O/activated charcoal [52], 2-chloro-4,6-dimethoxy-1,3,5-triazine [53], melamine trisulfonic acid [54], thiamine hydrochloride [55], hafnium(IV) bis(perfluoro-octanesulfonyl)imide complex supported on fluorous silica gel [56], ultrasound [57], ultrasound/[bmim]BF4 [58], and ultrasound/nano CeO2 [59] are some of the useful protocols which have been reported for the titled transformation.

HFIP covers the C18 stationary phase with a fluorous layer [52], shifting the stationary phase properties nearer to a fluorinated stationary phase.

Edwards, "Extraction and quantitation of ketones and aldehydes from mammalian cells using fluorous tagging and capillary LC-MS," Analytical Chemistry, vol.

"Exploring Fluorous Affinity by Liquid Chromatography," Anal.

(+)-Roccellaric acid 7 was first found as a minor compound in Cetraria islandica using a "fluorous tag-catch and release strategy", as it normally co-elutes with protolichesterinic acid in TLC (Horhant et al.

Cai, "Mannich-type reactions of aromatic aldehydes, anilines, and methyl ketones in fluorous biphase systems created by rare earth (III) perfluorooctane sulfonates catalysts in fluorous media," Journal of Fluorine Chemistry, vol.

Biphasic fluorous media represent a further promising technique for green catalysis [71].

Dembinski, "Thionation using fluorous Lawesson's reagent," Organic Letters, vol.

After introductory chapters, he covers perfluoroalkylation; selected fluorinated structures and reaction types; the chemistry of highly fluorinated olefins; fluorous chemistry; fluorous synthesis and combinatorial chemistry; halofluororcarbons, hydroflurorocarbons, and related compounds; and pharmaceutical and other biomedical applications.